When proposing a new template, you should set it to real-time and set the boot you’d like to see real-time games on that template use. Multi-day boot times will always be 25 hours. Be sure to set the number of players in the template based on how many players should be in the game (add 2 players/open seats for a 1v1, more for FFAs or team games). Note that autoboot and respect vacations are always enabled.
I like the quickmatches so far but i'm personally a slower player so 25 hours is really something i prefer to avoid when choosing open games i'd be joining.
So my personal proposal would be to add a 72-hour boot section as well besides the 25 and RT there already is for the players like me who really need it.
With 25 hours the problem i see is i might have today time to play between 10 and 11 AM and the day after only between 4 and 5 PM so if my opponent commits his turn before 3PM today i'll get booted from that game.